SELF-ASSEMBLY OF A FERROMAGNETICALLY COUPLED MANGANESE(II) TETRAMER

被引：112

作者：

AMOROSO, AJ

JEFFERY, JC

JONES, PL

MCCLEVERTY, JA

THORNTON, P

WARD, MD

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

[2] UNIV LONDON QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期

关键词：

COMPLEXES WITH NITROGEN LIGANDS; MAGNETIC PROPERTIES; MANGANESE COMPOUNDS; SELF-ASSEMBLY; STRUCTURE ELUCIDATION;

D O I：

10.1002/anie.199514431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

π‐Stacking interactions between adjacent aromatic ligand fragments of L− separated by approximately 3.4 Å provides a pathway for weak ferromagnetic coupling in the tetramer [Mn4L4](PF6)4 (1). The cavity of L− is too large for a single MnII ion; instead the tetramer 1 comprises a Mn4 tetrahedron, with a ligand L− attached to each triangular face. In the self‐assembly of 1, eight components are combined under the formation of 24 MnN bonds to give a complicated structure. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1443 / 1446

页数：4

共 45 条

[1] AMOROSO A, UNPUB
[2] SYNTHESIS OF THE NEW TRIPODAL LIGAND TRIS-[3-(2'-PYRIDYL)PYRAZOL-1-YL]HYDROBORATE, AND THE CRYSTAL-STRUCTURE OF ITS EUROPIUM(III) COMPLEX
AMOROSO, AJ
THOMPSON, AMC
JEFFERY, JC
JONES, PL
MCCLEVERTY, JA
WARD, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (24) : 2751 - 2752
[3] SYNTHESIS AND CHARACTERIZATION OF THE HOMOLEPTIC ARYLOXIDES [M(O(2,4,6-T-BU3C6H2))2]2 (M = MN, FE), THE ADDUCTS [MN(OCPH3)2(PY)2] AND [FE(OCPH3)2(THF)2], AND THE MIXED COMPLEX [FE(N(SIME3)2)(MU-O(2,4,6-T-BU3C6H2))]2 - EVIDENCE FOR PRIMARILY IONIC M-O BONDING
BARTLETT, RA
ELLISON, JJ
POWER, PP
SHONER, SC
[J]. INORGANIC CHEMISTRY, 1991, 30 (14) : 2888 - 2894
[4] MULTICOMPONENT SELF-ASSEMBLY - SPONTANEOUS FORMATION OF A CYLINDRICAL COMPLEX FROM 5 LIGANDS AND 6 METAL-IONS
BAXTER, P
LEHN, JM
DECIAN, A
FISCHER, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (01): : 69 - 72
[5] BAXTER P, 1993, ANGEW CHEM, V105, P92
[6] Baxter P. N. W., 1994, ANGEW CHEM, V33, P2284
[7] BAXTER PNW, 1994, ANGEW CHEM INT EDIT, V33, P2284, DOI 10.1002/anie.199422841
[8] BERNARDINELLI G, 1992, ANGEW CHEM INT EDIT, V31, P1622
[9] BERNARDINELLI G, 1992, ANGEW CHEM, V104, P1626
[10] POTENTIAL BUILDING-BLOCKS FOR MOLECULAR FERROMAGNETS - [MN12O12(O2CPH)16(H2O)4] WITH A S=14 GROUND-STATE
BOYD, PDW
LI, QY
VINCENT, JB
FOLTING, K
CHANG, HR
STREIB, WE
HUFFMAN, JC
CHRISTOU, G
HENDRICKSON, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) : 8537 - 8539

← 1 2 3 4 5 →