DYNAMICS OF FERROCENE ENCLATHRATED IN DEOXYCHOLIC-ACID AS STUDIED BY SASS (SWITCHING-ANGLE SAMPLE SPINNING) NMR-SPECTROSCOPY

被引：7

作者：

IMASHIRO, F

KITAZAKI, N

KUWAHARA, D

NAKAI, T

TERAO, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 02期

关键词：

D O I：

10.1039/c39910000085

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A C-13 chemical-shift powder pattern for ferrocene enclathrated in the deoxycholic acid channel selectively observed by SASS NMR reveals that the included ferrocene molecule is rotating around its five-fold axis; moreover, the axis is rotating on a cone with a half-angle of 18-degrees at ambient temperature.

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页码：85 / 86

页数：2

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