THE STRUCTURE OF THE ADDUCT BETWEEN 2-ETHOXYCYANOPYRIDINE AND COPPER(II) CHLORIDE

被引：11

作者：

BYERS, P

DREW, MGB

HUDSON, MJ

ISAACS, NS

UPADHAYA, A

MADIC, C

机构：

[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

[2] CENFAR,COMMISSARIAT ENERGIE ATOM,F-92265 FONTENAY ROSES,FRANCE

来源：

POLYHEDRON | 1994年 / 13卷 / 03期

关键词：

D O I：

10.1016/S0277-5387(00)81643-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The presence of the alkoxylated intermediate formed by the addition of alcohol to the cyano group has been confirmed by the isolation of the dimeric copper(II) complex [CuCl2C8N2OH10](2), in which each five coordinate copper atom is bound to two chlorine and two nitrogen atoms in a square planar arrangement. In addition, there are weak axial interactions between the copper and chlorine atoms which allow the formation of a centrosymmetric dimer in which the copper atom has a square planar coordination.

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页码：345 / 347

页数：3

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