REVERSIBLE MIGRATION OF A COORDINATED MERCAPTO LIGAND ON TO A METAL-BOUND ALKYNE TO GIVE ETA-2-VINYL COMPLEXES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [WC(CF3).C(CF3)SPRI(CF3C=CCF3)(ETA-5-C5H5)]

被引：41

作者：

CARLTON, L

DAVIDSON, JL

MILLER, JC

MUIR, KW

机构：

[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

[2] UNIV GLASGOW,DEPT CHEM,GLASGOW G12 8QQ,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1984年 / 01期

关键词：

D O I：

10.1039/c39840000011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：11 / 13

页数：3

共 11 条

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[2] THE ROLE OF METALLACYCLOPROPENES IN THE FORMATION OF ALKYLIDYNE COMPLEXES - EVIDENCE FOR A 1,2-TRIMETHYLSILYL SHIFT AND THE X-RAY CRYSTAL-STRUCTURE OF [MO=C(SIME3)CH2[P(OME)3]2(ETA-5-C9H7)]
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[3] REACTIONS OF MOLYBDENUM AND TUNGSTEN CARBONYLCYCLOPENTADIENYL HYDRIDES WITH ALPHA-AMINO ACETYLENES .2.
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[4] SYNTHESES INVOLVING COORDINATIVELY - UNSATURATED CYCLOPENTADIENYL-MOLYBDENUM AND TUNGSTEN COMPLEXES - MOLECULAR AND CRYSTAL-STRUCTURE OF [MO.C(CF3)-C(CF3).C5H5(CF3C2CF3) (ETA-5-C5H5)]
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[5] CO-ORDINATIVELY UNSATURATED ALKYNE COMPLEXES OF MOLYBDENUM AND TUNGSTEN - REACTIONS OF [MCL(CF3C=CCF3)2(ETA-C5H5)] (M = MO OR W) WITH HETEROCYCLIC THIOLATES LEADING TO ETA-2-VINYL COMPLEXES
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[6] ISOMERISM AND FLUXIONAL BEHAVIOR IN ETA-2-VINYL COMPLEXES RESULTING IN INVERSION OF CONFIGURATION AT AN ASYMMETRIC CARBON-ATOM - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2 ISOMERIC FORMS OF [MOCL[ETA-2-C(CF3)C(CF3)(PET3)](CF3C=CCF3)(ETA-5-C5H5)]
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[7] STABILIZATION OF VINYLIC INTERMEDIATES IN THE ADDITION, CYCLIZATION, AND OLIGOMERIZATION REACTIONS OF ALKYNES BY COORDINATION TO MOLYBDENUM AND TUNGSTEN - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [W(SC6H4ME-P)(ETA-2-C(CF3).C(CF3)PET3)(ETA-2-CF3C=CCF3)(ETA-C5H5)] AND [WCL(ETA-2-C(CF3).C(CF3)CNBUT)(ETA-2-CF3C=CCF3)(ETA-C5H5)N
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (17) : 1025 - 1027
[8] FORMATION OF NOVEL ETA-2-VINYL COMPLEXES BY NUCLEOPHILIC-ATTACK AT COORDINATED HEXAFLUOROBUT-2-YNE - IMPLICATIONS FOR THE STEREOCHEMISTRY OF ADDITION AND INSERTION REACTIONS OF COORDINATED ACETYLENES - CRYSTAL AND MOLECULAR-STRUCTURE OF [MO(SC5H4NC(CF3).C(CF3))-(CF3C=CCF3)(ETA-C5H5)]
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