NICKEL CATALYZED ELECTROSYNTHESIS OF ANTI-INFLAMMATORY AGENTS .2. MONITORING OF THE ELECTROLYSES BY HPLC ANALYSIS - ROLE OF THE CATALYST

被引：21

作者：

FAUVARQUE, JF ^{[1
]}

JUTAND, A ^{[1
]}

FRANCOIS, M ^{[1
]}

PETIT, MA ^{[1
]}

机构：

[1] UNIV PARIS 11,RECH MACROMOLEC LAB,CNRS,U607,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1988年 / 18卷 / 01期

关键词：

ACIDS - Chromatographic Analysis - CATALYSTS - Nickel - ELECTROLYSIS - Monitoring;

D O I：

10.1007/BF01016214

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A method of analysis has been developed by HPLC to monitor the progress of the electrosynthesis of aryl-2 propionic acids. This method elucidates the role of the nickel catalyst. It is found that HPLC is a very convenient method for analyzing electrochemical syntheses. The direct injection into the HPLC system of samples withdrawn from the solution permits the identification and quantification of the products and reagents at the end of, or during the electrolyses. The analysis of the evolution of the electrosynthesis enables a better understanding of the role of the nickel catalyst.

引用

页码：116 / 119

页数：4