A WHITLOCKITE-LIKE CALCIUM COPPER PHOSPHATE

被引：13

作者：

YANOV, OV

MOROZOV, VA

VIETING, BN

IVANOV, LN

LAZORYAK, BI

机构：

[1] Chemical Department, Moscow State University, 119899 Moscow, GSP

来源：

MATERIALS RESEARCH BULLETIN | 1994年 / 29卷 / 12期

关键词：

PHOSPHATES; COPPER; CALCIUM; WHITLOCKITE;

D O I：

10.1016/0025-5408(94)90155-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new calcium copper orthophosphate Ca10Cu(PO4)7 has been prepared and characterized. The compound is stable in the temperature range of 300-1200 K in inert atmosphere or 300-680 K in air. The compound Ca10Cu(PO4)7 is crystallized in the rhombohedral system with whitlockite-type structure. The space group is R3c, the lattice constants are: a=10.442(1), c=37.39(1)angstrom, V=3531(1)angstrom3. There are two different copper sites in the structure.

引用

页码：1307 / 1314

页数：8

共 23 条

[1] DETERMINATION OF THE ACTIVE-CENTER IN CALCIUM-NICKEL PHOSPHATE DEHYDROGENATION CATALYST [J].