MULTISTEP REDOX SYSTEMS .55. CRYSTAL-STRUCTURE OF THE CT-COMPLEX 2,5-ME2-DCNQI TTF FROM N,N'-DICYANO-2,5-DIMETHYL-1,4-BENZOQUINONE DIIMINE AND TETRATHIAFULVALENE AND OF THE ACCEPTOR 2,5-ME2-DCNQI

被引：36

作者：

AUMULLER, A

ERK, P

HUNIG, S

HADICKE, E

PETERS, K

VONSCHNERING, HG

机构：

[1] UNIV WURZBURG,INST ORGAN CHEM,W-8700 WURZBURG,GERMANY

[2] BASF AG,W-6700 LUDWIGSHAFEN,GERMANY

[3] MAX PLANCK INST FESTKORPERFORSCH,W-7000 STUTTGART 80,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 09期

关键词：

PI-ACCEPTOR; CHARGE-TRANSFER COMPLEX; 1,4-BENZOQUINONE DIIMINE, N,N'-DICYAN, 2,5-DIMETHYL; TETRATHIAFULVALENE;

D O I：

10.1002/cber.19911240920

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the title compound is described and discussed in terms of a neutral non-conducting mixed-stack CT complex. X-ray data for the acceptor 2,5-Me2-DCNQI are given for comparison.

引用

页码：2001 / 2004

页数：4

共 13 条

[1] ORGANIC METALS - N,N'-DICYANO-1,4-BENZOQUINONEDIIMINES AS ACCEPTORS IN CHARGE-TRANSFER COMPLEXES [J].

ANDREETTI, GD ;

BRADAMANTE, S ;

BIZZARRI, PC ;

PAGANI, GA .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 120 (1-4) :309-314

[2]

AUMMULLER A, 1987, LIEBIGS ANN CHEM, P997

[3] MULTISTEP REDOX SYSTEMS .54. CONDUCTING CT COMPLEXES OF TETRATHIAFULVALENE (TTF) WITH TETRACYANOBENZOQUINODIMETHANE (TCNQ) AND N,N'-DICYANOBENZOQUINODIIMINE (DCNQI) - A COMPARISON [J].

AUMULLER, A ;

ERK, P ;

HUNIG, S ;

VONSCHUTZ, JU ;

WERNER, HP ;

WOLF, HC ;

KLEBE, G .

CHEMISCHE BERICHTE, 1991, 124 (06) :1445-1451

[4]

AUMULLER A, 1986, LIEBIGS ANN CHEM, P142

[5]

AUMULLER A, 1985, THESIS U WURZBURG

[6] CRYSTAL AND MOLECULAR STRUCTURE OF AROMATIC SULPHUR COMPOUND 2,2'-BI-1,3-DITHIOLE - EVIDENCE FOR D-ORBITAL PARTICIPATION IN BONDING [J].

COOPER, WF ;

KENNY, NC ;

EDMONDS, JW ;

NAGEL, A ;

WUDL, F ;

COPPENS, P .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (16) :889-&

[7]

ERK P, 1989, THESIS U WURZBURG

[8] LATTICE ENERGY, STRUCTURE AND STABILITY OF 3-DIMENSIONAL TETRATHIAFULVALENIUM 7,7,8,8-TETRACYANOQUINODIMETHANIDE (TTF-TCNQ) MODELS WITH SEGREGATED AND MIXED STACKS [J].

GOVERS, HAJ .

ACTA CRYSTALLOGRAPHICA SECTION A, 1982, 38 (SEP) :703-707

[9]

HADDON RC, 1976, AUST J CHEM, V28, P2333

[10] MIXED-STACK COMPLEXES OF TETRATHIAFULVALENE - STRUCTURES OF THE CHARGE-TRANSFER COMPLEXES OF TTF WITH CHLORANIL AND FLUORANIL [J].

MAYERLE, JJ ;

TORRANCE, JB ;

CROWLEY, JI .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (DEC) :2988-2995

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