AN EASY AND FAST WAY TO DETERMINE THE ENANTIOMERIC PURITY OF SUBSTITUTED CYCLANONES

被引：44

作者：

ALEXAKIS, A

FRUTOS, JC

MANGENEY, P

机构：

[1] Laboratoire de Chimie des Organo-Eléments, CNRS UA 473 Université P. et M. Curie, F-75252 Paris Cedex 05, 4, Place Jussieu

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(00)82217-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The determination of the enantiomeric purity of 2 or 3-substituted cyclanones, particularly cyclohexanones, is conveniently achieved by derivatisation into cyclic aminals with commercially available (R, R)-1,2-diphenylethylenediamine. The derivatisation procedure is directly done into the NMR tube, instantaneously, and C-13 NMR allows an accurate measure of the ee.

引用

页码：2431 / 2434

页数：4

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