SOLUBLE ALUMINOSILICATES WITH FRAMEWORKS OF MINERALS

被引：87

作者：

MONTERO, ML ^{[1
]}

VOIGT, A ^{[1
]}

TEICHERT, M ^{[1
]}

USON, I ^{[1
]}

ROESKY, HW ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

ALUMINOSILICATES; SILANETRIOLS; ZEOLITES;

D O I：

10.1002/anie.199525041

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A silanetriol and organoaluminum compounds react smoothly to give aluminosilcates of the type shown, which are soluble in organic solvents. Their cubeshaped Al4Si4O12 groups represent the smallest building blocks of zeolite A. Perhaps compounds of this type will be used in the near future in rational solid‐state syntheses under mild conditions. R1 = (2,6‐iPr2C6H3)(SiMe3)N, R2 = 1,4‐dioxane, THF, alkyl group. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2504 / 2506

页数：3

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