SELECTIVE OXIDATION OF ALCOHOLS AND ALDEHYDES WITH HYDROGEN-PEROXIDE CATALYZED BY METHYLTRIOCTYLAMMONIUM TETRAKIS(OXODIPEROXOTUNGSTO)PHOSPHATE(3-) UNDER 2-PHASE CONDITIONS

被引：147

作者：

VENTURELLO, C

GAMBARO, M

机构：

[1] Istituto G. Donegani S.p.A.

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 20期

关键词：

D O I：

10.1021/jo00020a040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of methyltrioctylammonium tetrakis(oxodiperoxotungsto)phosphate(3-) (1c) in combination with hydrogen peroxide as the primary oxidant in an aqueous/organic biphase system provides a cheap, efficient, and versatile catalytic method for alcohol and aldehyde oxidation. By this method, a variety of water-insoluble primary and secondary alcohols and aldehydes were oxidized to carboxylic acids and ketones in good yields under mild conditions and after relatively short reaction times.

引用

页码：5924 / 5931

页数：8

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