THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE] DICHLORORUTHENIUM (II)

被引：12

作者：

FONTES, MRM

OLIVA, G

CORDEIRO, LAC

BATISTA, AA

机构：

[1] UNIV SAO PAULO,INST FIS QUIM SAO CARLOS,CP 369,CEP 13560,SAO CARLOS,SP,BRAZIL

[2] UNIV FED PARA,DEPT QUIM,BELEM,PARA,BRAZIL

[3] UNIV FED SAO CARLOS,DEPT QUIM,BR-13560 SAO CARLOS,SP,BRAZIL

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1993年 / 30卷 / 02期

关键词：

RUTHENIUM(II); DIPHOSPHINE; X-RAY STRUCTURE;

D O I：

10.1080/00958979308024664

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, trans-[Ru(dppp)2Cl2], crystallizes in the triclinic space group P1BAR, with a = 9.529(1), b = 11.071(1), c = 11.936(1)A, alpha = 71.967(9), beta = 72.879(6), gamma = 88.703(9)-degrees, V = 1141.1(2) angstrom3 and Z = 1. The structure was solved and refined to a final R = 0.039, for 3126 independently observed reflections with I > 3sigma (I). The ruthenium(II) ion is located on a crystallographic centre of symmetry and shows a distorted octahedral coordination with the chloride atoms in an exactly trans configuration.

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页码：125 / 129

页数：5

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