MOLECULAR CIS-TRANS SWITCHING IN AMPHIPHILIC MONOLAYERS CONTAINING AZOBENZENE MOIETIES

被引:44
作者
MAACK, J [1 ]
AHUJA, RC [1 ]
MOBIUS, D [1 ]
TACHIBANA, H [1 ]
MATSUMOTO, M [1 ]
机构
[1] NATL INST MAT & CHEM RES,TSUKUBA,IBARAKI 305,JAPAN
关键词
D O I
10.1016/0040-6090(94)90514-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel principle of molecular architecture for monolayers containing azobenzene moieties is presented which allows the chromophores to be organized with a high density and with sufficient mobility for photochemical change. This monolayer represents a new medium for a data storage system; each single azobenzene group is in principle capable of storing the information of 1 bit. The physical properties of this monolayer have been investigated at the air-water interface. Data storage in the micrometer range is demonstrated with a single monolayer transferred on glass.
引用
收藏
页码:122 / 126
页数:5
相关论文
共 17 条
[1]  
AHUJA RC, UNPUB J PHYS CHEM
[2]   The dipole moments of cis- and trans-azobenzenes and of some related compounds [J].
Hartley, GS ;
Le Fevre, RJW .
JOURNAL OF THE CHEMICAL SOCIETY, 1939, :531-535
[4]   BREWSTER-ANGLE MICROSCOPY OF LB FILMS ON SOLID SUBSTRATES [J].
HONIG, D ;
MOBIUS, D .
CHEMICAL PHYSICS LETTERS, 1992, 195 (01) :50-52
[5]   REFLECTOMETRY AT THE BREWSTER-ANGLE AND BREWSTER-ANGLE MICROSCOPY AT THE AIR-WATER-INTERFACE [J].
HONIG, D ;
MOBIUS, D .
THIN SOLID FILMS, 1992, 210 (1-2) :64-68
[6]  
MAACK J, UNPUB J PHYS CHEM
[7]  
MOBIUS D, 1969, BERICH BUNSEN GESELL, V73, P845
[8]   ORIENTATION OF CHROMOPHORES IN MONOLAYERS AND MULTILAYERS OF AZOBENZENE DERIVATIVES WITH LONG ALKYL CHAINS [J].
NAKAHARA, H ;
FUKUDA, K .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 93 (02) :530-539
[9]   STARS, STRIPES AND SHELLS IN MONOLAYERS - SIMULATION OF THE MOLECULAR ARRANGEMENT IN SCHLIEREN STRUCTURES [J].
OVERBECK, GA ;
HONIG, D ;
MOBIUS, D .
THIN SOLID FILMS, 1994, 242 (1-2) :213-219
[10]   PHOTOCHROMISM IN MONOLAYERS [J].
POLYMEROPOULOS, EE ;
MOBIUS, D .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1979, 83 (12) :1215-1222