ON THE POTENTIAL IMPORTANCE OF THE GAS-PHASE REACTION CH3O2 + CLO -] CLOO + CH3O AND THE HETEROGENEOUS REACTION HOCL + HCL -] H2O + CL2 IN OZONE HOLE CHEMISTRY

被引:118
作者
CRUTZEN, PJ [1 ]
MULLER, R [1 ]
BRUHL, C [1 ]
PETER, T [1 ]
机构
[1] UNIV STOCKHOLM,INST METEOROL,S-10691 STOCKHOLM,SWEDEN
关键词
D O I
10.1029/92GL01172
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
We call attention to the great importance of the gas phase reaction ClO + CH3O2 --> ClOO + CH3O and the heterogeneous reaction HCl + HOCl --> Cl2 + H2O on polar stratospheric cloud (PSC) particles. These reactions may accomplish the almost complete conversion of HCl into ClO(x) radicals, thus leading to rapid destruction of ozone.
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页码:1113 / 1116
页数:4
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