(MU-1-CP)TC(NAR)3 - SYNTHESIS AND STRUCTURE

被引：29

作者：

BURRELL, AK

BRYAN, JC

机构：

[1] LOS ALAMOS NATL LAB,INORGAN & STRUCT CHEM GRP INC-1,LOS ALAMOS,NM 87545

[2] LOS ALAMOS NATL LAB,NUCL & RADIOCHEM GRP INC-15,LOS ALAMOS,NM 87545

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 11期

关键词：

D O I：

10.1021/om00059a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of KCp with Tcl(NAr)3 (Ar = 2,6-diisopropylphenyl) rapidlY forms (eta1-Cp)Tc(NAr)3. A single-crystal X-ray determination confirmed the eta1 nature of the cyclopentadienyl ligand. When Tcl(NAr)3 is treated with an excess of KCp, a second cyclopentadienyl group is added to the metal, giving K[Cp2Tc(NAr)3].

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页码：3501 / 3503

页数：3

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