THE FIRST DINUCLEAR COBALT-RHENIUM CLUSTER COMPOUND - HEXACARBONYLBIS(MU-DICYCLOHEXYLPHOSPHANIDO)COBALTRHENIUM

被引：3

作者：

FLORKE, U

HAUPT, HJ

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193005013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound [hexacarbonyl-1 kappa(4)C,2 kappa(2)C-bis(mu-dicyclohexylphosphido-1:2 kappa(2)P)cobaltrhenium(Co-Re) 0.5-methanol solvate] belongs to a type of edge-linked tetrahedron-octahedron coordination complex. The molecule has local C-2 nu symmetry with ecliptic conformation of the carbonyl ligands at both metal centres, and a Co-Re single-bond length of 2.786 (1) Angstrom.

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页码：1906 / 1908

页数：3

相关论文

共 9 条

[1] CAMBRIDGE CRYSTALLOGRAPHIC DATA CENTER - COMPUTER-BASED SEARCH, RETRIEVAL, ANALYSIS AND DISPLAY OF INFORMATION [J].

ALLEN, FH ;

BELLARD, S ;

BRICE, MD ;

CARTWRIGHT, BA ;

DOUBLEDAY, A ;

HIGGS, H ;

HUMMELINK, T ;

HUMMELINKPETERS, BG ;

KENNARD, O ;

MOTHERWELL, WDS ;

RODGERS, JR ;

WATSON, DG .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (OCT) :2331-2339

[2] MOLECULAR STRUCTURES OF [(C6H5)2PCOC5H5]2 AND [C6H5)2PNIC5H5]2 . AN ASSESSMENT OF INFLUENCE OF A METAL-METAL BOND ON MOLECULAR GEOMETRY OF AN ORGANOMETALLIC LIGAND-BRIDGED COMPLEX [J].

COLEMAN, JM ;

DAHL, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (03) :542-+

[3] DIMANGANESE OCTACARBONYL COMPOUNDS WITH BRIDGING CYCLOHEXYLPHOSPHANES [J].

FLORKE, U ;

HAUPT, HJ .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :374-376

[4] DEPROTONATION OF RE2(MU-H)(MU-PPH2)(CO)8 FOR SYNTHESIS OF MIXED RHENIUM-GOLD CLUSTERS WITH RE2AUN CORES (N = 1-3) [J].

HAUPT, HJ ;

HEINEKAMP, C ;

FLORKE, U .

INORGANIC CHEMISTRY, 1990, 29 (16) :2955-2963

[5] THERMOLYSIS OF RE2(CO)10-N(P(C6H5)3)N (N = 1,2) [J].

HAUPT, HJ ;

BALSAA, P ;

FLORKE, U .

INORGANIC CHEMISTRY, 1988, 27 (02) :280-286

[6]

JEFFERY JC, 1985, J CHEM SOC DALTON, P2001, DOI 10.1039/dt9850002001

[7]

KELLER E, 1978, Z NATURFORSCH B, V33, P537

[8] PARST - A SYSTEM OF FORTRAN ROUTINES FOR CALCULATING MOLECULAR-STRUCTURE PARAMETERS FROM RESULTS OF CRYSTAL-STRUCTURE ANALYSES [J].

NARDELLI, M .

COMPUTERS & CHEMISTRY, 1983, 7 (03) :95-98

[9]

SHELDRICK GM, 1990, SHELXTL PLUS STRUCTU