CARBON-MONOXIDE HYDROGENATION OVER CARBON-SUPPORTED COBALT OR RUTHENIUM CATALYSTS - PROMOTING EFFECTS OF MAGNESIUM, VANADIUM AND CERIUM OXIDES

被引：79

作者：

GUERRERORUIZ, A ^{[1
]}

SEPULVEDAESCRIBANO, A ^{[1
]}

RODRIGUEZRAMOS, I ^{[1
]}

机构：

[1] CSIC,INST CATALISIS & PETROLEOQUIM,E-28049 MADRID,SPAIN

来源：

APPLIED CATALYSIS A-GENERAL | 1994年 / 120卷 / 01期

关键词：

CARBON MONOXIDE HYDROGENATION; CERIA PROMOTER; COBALT CARBON CATALYSTS; MAGNESIA PROMOTER; RUTHENIUM CARBON; TEMPERATURE-PROGRAMMED REDUCTION; VANADIA PROMOTER;

D O I：

10.1016/0926-860X(94)80334-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The promoting effects of magnesium, vanadium and cerium oxides on cobalt and ruthenium/carbon catalysts in the hydrogenation of carbon monoxide have been compared. The reducibility of the promoted and unpromoted catalysts was investigated by temperature-programmed reduction. In all cases the added oxide promoter enhanced the specific activity and the selectivity for alkenes and long chain hydrocarbons. These results are discussed on the basis of a general mechanism of promotion.

引用

页码：71 / 83

页数：13

共 39 条

[1] TEMPERATURE-PROGRAMMED REDUCTION OF COO/AL2O3 CATALYSTS
ARNOLDY, P
MOULIJN, JA
[J]. JOURNAL OF CATALYSIS, 1985, 93 (01) : 38 - 54
[2] INFLUENCE OF THE SUPPORT ON THE CATALYTIC PROPERTIES OF NICKEL CERIA IN CARBON-MONOXIDE AND BENZENE HYDROGENATION
BARRAULT, J
ALOUCHE, A
PAULBONCOUR, V
HILAIRE, L
PERCHERONGUEGAN, A
[J]. APPLIED CATALYSIS, 1989, 46 (02): : 269 - 279
[3] HYDROGENATION OF CARBON-MONOXIDE ON CARBON-SUPPORTED COBALT RARE-EARTH CATALYSTS
BARRAULT, J
GUILLEMINOT, A
ACHARD, JC
PAULBONCOUR, V
PERCHERONGUEGAN, A
[J]. APPLIED CATALYSIS, 1986, 21 (02): : 307 - 312
[4] MECHANISM OF HYDROCARBON SYNTHESIS OVER FISCHER-TROPSCH CATALYSTS
BILOEN, P
SACHTLER, WMH
[J]. ADVANCES IN CATALYSIS, 1981, 30 : 165 - 216
[5] PROMOTING EFFECTS OF THORIA AND MOLYBDENA ON COBALT CATALYSTS IN THE HYDROGENATION OF CO
CHEN, YZ
WANG, TH
[J]. CATALYSIS LETTERS, 1993, 22 (03) : 165 - 177
[6] FERNANDEZMORALE.I, 1985, APPL CATAL, V14, P159
[7] AN XPS STUDY OF METAL SUPPORT INTERACTIONS ON PD/SIO2 AND PD/LA2O3
FLEISCH, TH
HICKS, RF
BELL, AT
[J]. JOURNAL OF CATALYSIS, 1984, 87 (02) : 398 - 413
[8] METHANATION AND FISCHER-TROPSCH STUDIES ON POTASSIUM-PROMOTED SILICA-SUPPORTED RU CATALYSTS
GONZALEZ, RD
MIURA, H
[J]. JOURNAL OF CATALYSIS, 1982, 77 (02) : 338 - 347
[9] THE ROLE OF NITROGEN AND OXYGEN-SURFACE GROUPS IN THE BEHAVIOR OF CARBON-SUPPORTED IRON AND RUTHENIUM CATALYSTS
GUERRERORUIZ, A
RODRIGUEZRAMOS, I
RODRIGUEZREINOSO, F
MORENOCASTILLA, C
LOPEZGONZALEZ, JD
[J]. CARBON, 1988, 26 (04) : 417 - 423
[10] GUERRERORUIZ A, 1992, STUD SURF SCI CATAL, V72, P203

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