A VIVID MODEL ILLUSTRATING CHIRAL RECOGNITION INDUCED BY ACHIRAL STRUCTURES

被引：45

作者：

DAVANKOV, VA

MEYER, VR

RAIS, M

机构：

[1] RAIS GRAF,CH-3037 HERRENSCHWANDEN,SWITZERLAND

[2] UNIV BERN,INST ORGAN CHEM,CH-3012 BERN,SWITZERLAND

来源：

CHIRALITY | 1990年 / 2卷 / 04期

关键词：

chiral separations; didactic model; enantioselectivity; ligand‐exchange chromatography; three‐point model;

D O I：

10.1002/chir.530020403

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

If diastereomeric complexes are adsorbed on a surface or if they include a molecule of solvent, two points of attractive interaction between the chiral species of the complex can be sufficient for mutual chiral recognition of these species. In special cases even one single point of interaction is sufficient. This extension of the three‐point contact rule of Dalgliesh, first observed in chiral ligand‐exchange chromatogrphy, can be demonstrated by using hands. Copyright © 1990 Wiley‐Liss, Inc.

引用

页码：208 / 210

页数：3

共 7 条

[1] THE OPTICAL RESOLUTION OF AROMATIC AMINO-ACIDS ON PAPER CHROMATOGRAMS [J].