DESIGN, SPECIFICATIONS AND APPLICATION OF A HIGH-PRESSURE DSC CELL

被引：17

作者：

BLANKENHORN, K

HOHNE, GWH

机构：

[1] Sektion für Kalorimetrie, Universität Ulm, D 7900 Ulm

来源：

THERMOCHIMICA ACTA | 1991年 / 187卷

关键词：

D O I：

10.1016/0040-6031(91)87196-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The construction of a high pressure DSC measuring head for the Perkin-Elmer DSC-7 is presented. The DSC cell is developed to work in a range of temperature from 290 to 570 K at a maximum pressure of 500 MPa using different silicon oils as pressure medium. This calorimeter works with the common heating rates from 0, 1 K/min to 30 K/min. The noise of the base line is about 50-100-mu-W depending on the pressure in question. The repeatability of the base line amounts to 2-3 mW. The new high pressure cell is especially useful for DSC measurements in polymer science preliminary results are presented.

引用

页码：219 / 224

页数：6