[VO(N-(2-OXIDO-1-NAPHTHYLMETHYLENE)-L-ALA)OBU(S)(HOBU(S))] - CHARACTERIZATION OF A COMPLEX CONTAINING 4 CENTERS OF CHIRALITY

被引：63

作者：

FULWOOD, R ^{[1
]}

SCHMIDT, H ^{[1
]}

REHDER, D ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,D-20146 HAMBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 14期

关键词：

D O I：

10.1039/c39950001443

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of vanadyl sulfate, L-alanine and 2-hydroxynaphthaldehyde with subsequent aeration in D,L-sec-butyl alcohol leads to the Schiff base V-V complex [VO{N-(2-oxido-1-naphthylmethylene)-L-ala}OBu(s)(HOBu(s))] which, in solution, exists in at least three diastereoisomers (V-51 NMR evidence), and crystallizes with the ASRR and CSSS isomers in the same asymmetric unit.

引用

页码：1443 / 1444

页数：2

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