OXIDATION REACTIONS USING UREA HYDROGEN-PEROXIDE - A SAFE ALTERNATIVE TO ANHYDROUS HYDROGEN-PEROXIDE

被引：221

作者：

COOPER, MS ^{[1
]}

HEANEY, H ^{[1
]}

NEWBOLD, AJ ^{[1
]}

SANDERSON, WR ^{[1
]}

机构：

[1] LAPORTE RES & DEV,INTEROX RES & DEV,WIDNES,CHESHIRE,ENGLAND

来源：

SYNLETT | 1990年 / 09期

关键词：

D O I：

10.1055/s-1990-21156

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Urea-hydrogen peroxide (UHP) alone or in combination with carboxylic anhydrides has been shown to serve as a valuable alternative to anhydrous hydrogen peroxide: the range of substrates oxidised include alkenes (epoxidation), ketones (Baeyer-Villiger reaction), sulphides (to sulphones), nitrogen heterocycles (to N-oxides), and aromatic hydrocarbons (to phenols). © 1990 Georg Thieme Verlag. All rights reserved.

引用

页码：533 / 535

页数：3

共 22 条

[1] ARCUS CL, 1964, J CHEM SOC, P5995
[2] BACH RD, 1981, ORG SYNTH, V60, P63
[3] INTERDEPENDENCE OF MOLECULAR CONFORMATION AND CONJUGATION IN AROMATIC ETHERS .1.
BADDELEY, G
SMITH, NHP
VICKARS, MA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1956, (JUL): : 2455 - 2462
[4] Baker R., 1955, ORG SYNTH, V3, P141
[5] BROUGHAM P, 1987, SYNTHESIS-STUTTGART, P1015
[6] CHATTAWAY FD, 1931, J CHEM SOC, P2495
[7] 1,4-DIAZA[2.2.2]BICYCLOOCTANE-HYDROGEN PEROXIDE COMPLEX AS A SOURCE OF ANHYDROUS HYDROGEN-PEROXIDE - PREPARATION OF BIS(TRIALKYLSILYL) PEROXIDES
COOKSON, PG
DAVIES, AG
FAZAL, N
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 99 (02) : C31 - C32
[8] DANILOW S, 1927, CHEM BER, V60, P1050
[9] PEROXYTRIFLUOROACETIC ACID .4. THE EPOXIDATION OF OLEFINS
EMMONS, WD
PAGANO, AS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (01) : 89 - 92
[10] ZUR KENNTNIS ATHERISCHER OLE - DIE STRUKTUR DER SOGENANNTEN LINALOOLOXIDE
FELIX, D
MELERA, A
KOVATS, ES
SEIBL, J
[J]. HELVETICA CHIMICA ACTA, 1963, 46 (05) : 1513 - &

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