ORGANOTIN-SUBSTITUTED ORGANOSILOXANES - SYNTHESIS AND CHARACTERIZATION, INCLUDING THE CRYSTAL-STRUCTURE OF 1,3-BIS(TRIPHENYLSTANNOXY)-1,1,3,3-TETRAPHENYL-1,3-DISILOXANE

被引：20

作者：

BRISDON, BJ

MAHON, MF

MOLLOY, KC

SCHOFIELD, PJ

机构：

[1] School of Chemistry, University of Bath, Bath, BA2 7AY, Claverton Down

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

SILOXANES; STANNOXY; MOSSBAUER SPECTROSCOPY; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87048-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of linear 1,3-bis(triorganostannoxy)siloxanes (R(3)'SnO)R(2)SiOSiR(2)(OSnR(3)') (R = Me; Ph; R' = Ph, (n)Bu, c-C6H11) has been synthesised, and the compounds characterised by NMR (H-1, C-13, Si-29 and Sn-119) and Mossbauer spectroscopies. The structure of the homoleptic compound R = R' = Ph has been determined by an X-ray diffraction study.

引用

页码：145 / 151

页数：7

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