TANDEM CYCLOADDITION-ENZYMATIC TRANSESTERIFICATION - AN ENANTIOSELECTIVE DIELS-ALDER REACTION EQUIVALENT

被引:19
作者
ANDREU, C [1 ]
MARCO, JA [1 ]
ASENSIO, G [1 ]
机构
[1] FAC FARM VALENCIA,DEPT QUIM ORGAN,AVDA BLASCO IBANEZ 13,E-46010 VALENCIA,SPAIN
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 11期
关键词
D O I
10.1039/p19900003209
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tandem cycloaddition-enzymatic transesterification with pancreatic pig lipase or the lipase from Candida ciclindracea carried out in ethyl, vinyl, or isopropenyl acetate gives rise to optically active Diels-Alder type derivatives from symmetrical precursors with both high enantioselectivity and chemical yield.
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页码:3209 / 3210
页数:2
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