THE A2-PI-U[-X2-SIGMA-G+ SYSTEM OF N-2(+) - THE (3, 6) BAND OF N-14N-15+ AND FURTHER MEASUREMENTS OF THE (2, 5) BAND OF N-14N-14+

被引：13

作者：

HO, WC

JAGER, W

CRAMB, DT

OZIER, I

GERRY, MCL

机构：

[1] Department of Physics, The University of British Columbia, Vancouver

[2] Department of Chemistry, The University of British Columbia, Vancouver

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1992年 / 153卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0022-2852(92)90503-G

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The A2Πu ← X2Σg+ system for two isotopomers of N2+ has been observed near 2200 cm-1 using a velocity modulation diode laser spectrometer. For 14N15N+ and 14N14N+ the (3, 6) and (2, 5) bands have been measured, respectively. A static ac glow discharge has been used for the 14N15N+ studies. For the mixed isotopomer, these are the first measurements of the A-X system. For the normal isotopomer, the measurements extend previous observations. Spectroscopic constants for the A and X states of both isotopomers have been evaluated; they are compared with previous values for 14N14N+, and with values estimated for 14N15N+ by isotopic scaling from the normal isotopomer. © 1992.

引用

页码：692 / 700

页数：9

共 26 条

[1] PRODUCT DISTRIBUTIONS FOR SOME THERMAL-ENERGY CHARGE-TRANSFER REACTIONS OF RARE-GAS IONS [J].