FORMATION OF A HETEROMETALLIC (HG-GD) POLYMERIC COMPLEX OF 2-OXAZOLIDONE CONSISTING OF FUSED 16-MEMBERED AND 48-MEMBERED MACROCYCLIC RINGS - CRYSTAL-STRUCTURE OF [HG2(C3H4NO2)4GD(NO3)3]N

被引：10

作者：

CARRAD, LH

GOODGAME, DML

WILLIAMS, DJ

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2-Oxazolidone (LH = C3H5NO2) reacts with mercury(II) acetate and gadolinium(III) nitrate in methanol to form the polymeric complex [Hg2(C3H4NO2)4Gd(NO3)3]n which consists of a unique array of contiguous 16- and 48-membered macrocycles.

引用

页码：175 / 176

页数：2

共 5 条

[1] DIVERSITY OF STRUCTURAL TYPES IN POLYMERIC, HETEROMETALLIC COMPLEXES FORMED BY THE REACTION OF BIS(2-PYRROLIDONATO)MERCURY(II) WITH ZN-2+, CD-2+ AND HG-2+ IONS - X-RAY CRYSTAL-STRUCTURES OF [HG3ZN2(C4H6NO)6(NO3)3.33(CH3O)0.67]N AND [HG2(C4H6NO)2CL2]N (WHERE C4H6NO IS THE ANION OF 2-PYRROLIDONE)
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[2] METALATION OF BETA-PROPIOLACTAM - CRYSTAL-STRUCTURES OF HG(C3H4NO)2.H2O AND OF THE BIMETALLIC POLYMERIC 48-MEMBERED MACROCYCLIC COMPLEX [HG3(C3H4NO)6ER2(NO3)6]N
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[4] NOVEL BIMETALLIC MACROCYCLIC POLYMER STRUCTURES INCORPORATING DEPROTONATED 2-PYRROLIDONE BRIDGES - THE CRYSTAL-STRUCTURES OF [(HG2CU(C4H6NO)4)X2]N(X=NO3 OR CLO4)
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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (10): : 1044 - 1045
[5] GOODGAME DML, UNPUB POLYHEDRON

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