ANIONIC FRIES REARRANGEMENTS OF ESTERS OF ORTHO-IODOBENZYL ALCOHOLS - RAPID ROUTES TO ESTRONE METHYL-ETHER AND ITS 9-BETA EPIMER, AND ARYL NAPHTHALIDE LIGNANS

被引：17

作者：

HORNE, S ^{[1
]}

RODRIGO, R ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fast, general, low-temperature rearrangement of ortho-iodobenzyl esters, triggered by lithium-iodine exchange, leads to isobenzofurans which are intercepted in situ by inter and intramolecular Diels-Alder (IMDA) reactions to produce a variety of carbocycles including natural lignans and steroids.

引用

页码：164 / 166

页数：3

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