RADICAL TRANSLOCATION REACTIONS ACROSS AMIDES - 1,5-HYDROGEN-TRANSFER REACTIONS OF O-IODOBENZAMIDES AND N-(O-IODOBENZYL) AMIDES

被引：71

作者：

CURRAN, DP

LIU, HT

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 11期

关键词：

D O I：

10.1039/p19940001377

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radicals derived from N,N-disubstituted o-iodobenzamides undergo rapid 1.5-hydrogen-transfer reactions. The regioselectivity of these reactions is coupled to the rotamer population of the starting iodobenzamide. and the products vary with changing amide substituents. Related 1,5-hydrogen-transfer reactions are observed for N-alkyl-N-(o-iodobenzyl)-benzamides and -acetamides.

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页码：1377 / 1393

页数：17

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