A STABLE DICARBONYL(CYCLOOCTA-1,5-DIENE)-(ETA(1)-INDENYL)IRIDIUM INTERMEDIATE IN THE SUBSTITUTION-REACTION OF CYCLOOCTA-1,5-DIENE(ETA(5)-INDENYL)IRIDIUM WITH CARBON-MONOXIDE

被引：19

作者：

BELLOMO, S ^{[1
]}

CECCON, A ^{[1
]}

GAMBARO, A ^{[1
]}

SANTI, S ^{[1
]}

VENZO, A ^{[1
]}

机构：

[1] CNR,CTR STUDIO STATI MOLECOLARI RADICALICI & ECCITATI,I-35131 PADUA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 453卷 / 01期

关键词：

D O I：

10.1016/0022-328X(93)80344-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stable dicarbonyl(cycloocta-1,5-diene)(eta1-indenyl)iridium is formed by addition of CO to cyclooctadiene(eta5-indenyl)iridium in CD2Cl2 at low temperature. On raising the temperature above 250 K, the eta1 species changes quantitatively into dicarbonyl(eta5 -indenyl)iridium.

引用

页码：C4 / C6

页数：3

共 4 条

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