REVERSIBLE LITHIUM-GRAPHITE ANODES IN ROOM-TEMPERATURE CHLOROALUMINATE MELTS

被引:30
作者
CARLIN, RT [1 ]
FULLER, J [1 ]
HEDENSKOOG, M [1 ]
机构
[1] USAF ACAD,DEPT CHEM,COLORADO SPRINGS,CO 80840
关键词
D O I
10.1149/1.2054823
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Reduction of a graphite rod electrode in an AlCl3:EMIC:LiCl room-temperature molten salts leads to reversible lithium intercalation into the reduced graphite lattice. The cycling efficiency of the Li-graphite electrode ranges from 80 to 90% for current densities of 0.2 to 1 mA cm-2. In the staircase cyclic voltammogram the oxidation process occurs at a potential approximately 1 V positive of the reduction process.
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收藏
页码:L21 / L22
页数:2
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