ON THE REACTION-RATE OF THE FE-2+/FE-3+ REDOX COUPLE IN SULFATE-SOLUTION

被引：26

作者：

BOCHMANN, HG

VIELSTICH, W

机构：

[1] Univ of Bonn, Bonn, West Ger, Univ of Bonn, Bonn, West Ger

来源：

ELECTROCHIMICA ACTA | 1988年 / 33卷 / 06期

关键词：

ELECTROLYTES - Materials - GOLD AND ALLOYS - PALLADIUM AND ALLOYS - PLATINUM AND ALLOYS - SULFUR COMPOUNDS;

D O I：

10.1016/S0013-4686(98)80011-X

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The kinetic parameters of the Fe**2** plus /Fe**3** plus redox system have been determined on Pt, Pd, Au and on Tl//a//d/Pt in sulfate electrolyte using a turbulent pipe flow device. The results are in good agreement with data obtained by other methods in our laboratory as rotating disc, coulostatic and linear potential scan measurements. Differences in the rate constant obtained for different metals are explained by anion adsorption effects.

引用

页码：805 / 809

页数：5

共 16 条

[1] ELECTROCATALYSIS BY FOREIGN METAL MONOLAYERS - OXIDATION OF FORMIC-ACID ON PLATINUM [J].