SF4 - ELECTRON-AFFINITY DETERMINATION BY CHARGE-TRANSFER REACTIONS

被引：12

作者：

VIGGIANO, AA

MILLER, TM

MILLER, AES

MORRIS, RA

VANDOREN, JM

PAULSON, JF

机构：

[1] UNIV OKLAHOMA,DEPT PHYS & ASTRON,NORMAN,OK 73019

[2] UNIV OKLAHOMA,DEPT CHEM & BIOCHEM,NORMAN,OK 73019

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1991年 / 109卷

关键词：

D O I：

10.1016/0168-1176(91)85112-Y

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A selected-ion flow drift tube was used to conduct an extensive study of the negative ion/molecule reactions of SF4 and SF4-. Thirteen reactions proceed by electron transfer. Data from these reactions, and information from systems that do not react at all, are used to determine the electron affinity of SF4, EA(SF4) = 1.5 +/- 0.2 eV. Additional thermochemical data are used to determine the fluoride affinity of SF3, D(SF3-F-) = 1.8 +/- 0.3 eV.

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收藏

页码：327 / 338

页数：12

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