A NEW GEOMETRY FOR TETRAMANGANESE - FUSED OPEN CUBANES

被引:30
作者
GEDYE, C
HARDING, C
MCKEE, V
NELSON, J
PATTERSON, J
机构
[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND
[2] OPEN UNIV,DEPT CHEM,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND
[3] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND
关键词
D O I
10.1039/c39920000392
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of complex ions containing the [Mn4O2(L)2]2+ ion have been synthesised and structurally characterised; the Mn4O6 cores consist of two incomplete, face-sharing cubanes, EPR spectra are consistent with Mn(III) description and complex electrochemsitry is observed.
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页码:392 / 394
页数:3
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