PRODUCTION OF HYDROGEN-PEROXIDE AND ORGANIC HYDROPEROXIDES IN THE REACTION OF OZONE WITH NATURAL HYDROCARBONS IN AIR

被引：33

作者：

HATAKEYAMA, S

LAI, H

GAO, S

MURANO, K

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 08期

关键词：

D O I：

10.1246/cl.1993.1287

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of ozone with three kinds of olefins in air was studied. H2O2, CH3OOH, and HOCH2OOH were collected and analyzed with HPLC with a fluorometric detector. Direct reaction of CH2OO with H2O was found to be the source of HOCH2OOH. CH3OOH was formed only from the olefins which have a methyl group. Detailed reaction mechanisms are discussed.

引用

收藏

页码：1287 / 1290

页数：4

相关论文

共 15 条

[1] STUDIES ON THE FORMATION OF H2O2 IN THE OZONOLYSIS OF ALKENES [J].

BECKER, KH ;

BECHARA, J ;

BROCKMANN, KJ .

ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1993, 27 (01) :57-61

[2] IMPROVED AQUEOUS SCRUBBER FOR COLLECTION OF SOLUBLE ATMOSPHERIC TRACE GASES [J].

COFER, WR ;

COLLINS, VG ;

TALBOT, RW .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1985, 19 (06) :557-560

[3] REACTIONS OF CH2OO AND CH2(1A1) WITH H2O IN THE GAS-PHASE [J].

HATAKEYAMA, S ;

BANDOW, H ;

OKUDA, M ;

AKIMOTO, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (15) :2249-2254

[4] REACTIONS OF OZONE WITH 1-METHYLCYCLOHEXENE AND METHYLENECYCLOHEXANE IN AIR [J].

HATAKEYAMA, S ;

AKIMOTO, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (09) :2701-2703

[5] DETECTION OF METHYL, HYDROXYMETHYL AND HYDROXYETHYL HYDROPEROXIDES IN AIR AND PRECIPITATION [J].

HELLPOINTNER, E ;

GAB, S .

NATURE, 1989, 337 (6208) :631-634

[6] HYDROPEROXIDES IN PLANTS EXPOSED TO OZONE MEDIATE AIR-POLLUTION DAMAGE TO ALKENE EMITTERS [J].

HEWITT, CN ;

KOK, GL ;

FALL, R .

NATURE, 1990, 344 (6261) :56-58

[7] FORMATION AND OCCURRENCE OF ORGANIC HYDROPEROXIDES IN THE TROPOSPHERE - LABORATORY AND FIELD OBSERVATIONS [J].

HEWITT, CN ;

KOK, GL .

JOURNAL OF ATMOSPHERIC CHEMISTRY, 1991, 12 (02) :181-194

[8]

HEWITT N, 1992, ENVIRON SCI TECHNOL, V26, P1891

[9] REDETERMINATION OF THE RATE-CONSTANT FOR THE REACTION OF HO RADICALS WITH SO2 [J].

IZUMI, K ;

MIZUOCHI, M ;

YOSHIOKA, M ;

MURANO, K ;

FUKUYAMA, T .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1984, 18 (02) :116-118

[10] INVESTIGATING THE EFFECT OF HYDROGEN-PEROXIDE ON NORWAY SPRUCE TREES [J].

KETTRUP, AAF ;

KICINSKI, HG ;

MASUCH, G .

ANALYTICAL CHEMISTRY, 1991, 63 (21) :A1047-A1056