EFFICIENT SYNTHESIS OF RAC-(ETHYLENEBIS(INDENYL))ZRX(2) COMPLEXES VIA AMINE ELIMINATION

被引：172

作者：

DIAMOND, GM

RODEWALD, S

JORDAN, RF

机构：

[1] Department of Chemistry, University of Iowa, Iowa City

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 01期

关键词：

D O I：

10.1021/om00001a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The amine elimination reaction of 1,2-bis(3-indenyl)ethane (3) and Zr(NMe(2))(4) (2) affords pure rac-(EBI)Zr(NMe(2))(2) (4; EBI = 1,2-ethylenebis(1-indenyl)) in. 68% isolated yield. Treatment of 4 with 2 equiv of Me(2)-NH.HCl affords rac-(EBI)ZrCl2 (1) in 92% isolated yield. Compound 1 can, also be prepared directly from 2 and 3 in a ''one-pot'' synthesis in 69% isolated yield.

引用

页码：5 / 7

页数：3

共 41 条

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