Flash vacuum thermolysis of 1,5-bis-(1-chloroethenyl)anthracene. The thermal conversion of cyclopent[hi]aceanthrylene into cyclopent[hi]acephenanthrylene

被引：22

作者：

Sarobe, M ^{[1
]}

Snoeijer, JD ^{[1
]}

Jenneskens, LW ^{[1
]}

Zwikker, JW ^{[1
]}

Wesseling, J ^{[1
]}

机构：

[1] UNIV UTRECHT, DEBYE INST, DEPT PHYS ORGAN CHEM, 3584 CH UTRECHT, NETHERLANDS

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 52期

关键词：

D O I：

10.1016/0040-4039(95)02049-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Flash Vacuum Thermolysis of 1,5-bis-(1-chloroethenyl)anthracene (6) gives cyclopent[hi]aceanthrylene (2) which at T greater than or equal to 900 degrees C rearranges to cyclopent[hi]acephenanthrylene (1). This conversion occurs more readily than that of the monocyclopenta-fused aceanthrylene to acephenanthrylene.

引用

页码：9565 / 9566

页数：2

共 11 条

[1]

BOERE BB, 1990, RECL TRAV CHIM PAY B, V109, P463

[2] INTERCALATION AND BINDING OF CARCINOGENIC HYDROCARBON METABOLITES TO NUCLEIC-ACIDS [J].

HARVEY, RG ;

GEACINTOV, NE .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (02) :66-73

[3] RESOLUTION AND CONFIGURATIONAL STABILITY OF THE CHIRAL FULLERENES C-76, C-78, AND C-84 - A LIMIT FOR THE ACTIVATION-ENERGY OF THE STONE-WALES TRANSFORMATION [J].

HAWKINS, JM ;

NAMBU, M ;

MEYER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) :7642-7645

[4]

Lafleur Arthur L., 1993, Environmental Health Perspectives, V101, P146, DOI 10.2307/3431424

[5]

MULDER PPJ, 1993, RECL TRAV CHIM PAY B, V112, P255

[6]

NEILEN RHG, 1995, UNPUB J CHEM SOC CHE

[7]

PIATER MJ, 1994, TETRAHEDRON LETT, V35, P6147

[8]

SANGAIAH R, 1993, POLYCYCLIC AROMATIC

[9] PREPARATIVE FLASH VACUUM THERMOLYSIS - A SHORT SYNTHESIS OF CYCLOPENTA[C,D]PYRENE [J].

SAROBE, M ;

ZWIKKER, JW ;

SNOEIJER, JD ;

WIERSUM, UE ;

JENNESKENS, LW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) :89-90

[10]

SAROBE M, UNPUB

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