SYNTHESIS, BINDING-PROPERTIES AND CRYSTAL-STRUCTURE OF A HEMICARCERAND CONTAINING 4 PENTAMETHYLENEDIOXY GROUPS SPANNING 2 BOWLS

被引：11

作者：

BYUN, YS ^{[1
]}

ROBBINS, TA ^{[1
]}

KNOBLER, CB ^{[1
]}

CRAM, DJ ^{[1
]}

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90089

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001947

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hemicarcerand 1, whose synthesis from two tetrol bowls and four pentamethylene ditosylate molecules was templated by veratrole, was found to bind in solution (one-to-one) eighteen different guests; the crystal structure of 1.4MeCN is centrosymmetric; hemicarcerand 2, containing four hexamethylenedioxy groups, is also discussed.

引用

页码：1947 / 1948

页数：2

共 5 条

[1] HOST-GUEST COMPLEXATION .65. HEMICARCERANDS THAT ENCAPSULATE HYDROCARBONS WITH MOLECULAR-WEIGHTS GREATER-THAN 200
CRAM, DJ
JAEGER, R
DESHAYES, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) : 10111 - 10116
[2] CRAM DJ, 1994, MONOGRAPHS SUPRAMOLE, P1
[3] HOST-GUEST COMPLEXION .67. A HIGHLY ADAPTIVE AND STRONGLY BINDING HEMICARCERAND
ROBBINS, TA
KNOBLER, CB
BELLEW, DR
CRAM, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (01) : 111 - 122
[4] SHELDRICK GM, 1976, SHELX76
[5] HOST GUEST COMPLEXATION .56. SYNTHESES AND PROPERTIES OF SOLUBLE CARCEPLEXES
SHERMAN, JC
KNOBLER, CB
CRAM, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (06) : 2194 - 2204

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