A NOVEL HEXANUCLEAR HETEROPOLYPEROXO OXIDATION CATALYST - PREPARATION, X-RAY CRYSTAL-STRUCTURE AND REACTIONS OF [NME(4)](3)[(MEPO(3))(MEPO(2)(OH))W6O13(O-2)(4)(OH)(2)(OH)(2)]CENTER-DOT-4H(2)O

被引：27

作者：

GRIFFITH, WP

PARKIN, BC

WHITE, AJP

WILLIAMS, DJ

机构：

[1] Inorganic and Chemical Crystallographic Research Laboratories, Department of Chemistry, Imperial College of Science, Technology and Medicine, London

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 21期

关键词：

D O I：

10.1039/C39950002183

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the title compound, 1, reveals the presence of two distinct types of tungsten atom in which the four bearing peroxo groups have distorted pentagonal-bipyramidal geometries and the remaining two are octahedral; 1 is an effective catalyst for monoalkene epoxidation, and the oxidation of primary and secondary alcohols, with H2O2 as co-oxidant.

引用

页码：2183 / 2184

页数：2

共 8 条

[1]

Duckman M.H., Pope M.T., Chem. Rev, 94, (1994)

[2]

Dengel A.C., Griffith W.P., Parkin B.C., J. Chem. Soc, Dalton Trans, (1993)

[3]

Salles L., Aubry C., Thouvenot R., Robert F., Doremieux-Morin C., Chottard G., Ledon H., Jeannin V., Bregeault J.-M., Inorg. Chem, 33, (1994)

[4]

Venturello C., D'Aloisio R., Bart J., Ricci M., J. Mol. Catal, 32, (1985)

[5]

Griffith W.P., Parkin B.C., White A., Williams D.J., J. Chem. Soc, Dalton Trans, (1995)

[6]

Bailey A.J., Griffith W.P., Parkin B.C., J. Chem. Soc, Dalton Trans, (1995)

[7]

Duncan D.C., Chambers R.C., Hecht E., Hill C.J., J. Am. Chem. Soc, 117, (1995)

[8]

Release S., Siemens Analytical X-Ray Instruments, (1990)

← 1 →