A NEW MODE OF FORMATION OF A PHOSPHORUS PHOSPHORUS BOND - X-RAY CRYSTAL-STRUCTURE OF TETRAMETHYLDIPHOSPHANE MONOSULFIDE

被引：18

作者：

GRUBER, M ^{[1
]}

JONES, PG ^{[1
]}

SCHMUTZLER, R ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,HAGENRING 30,W-3300 BRAUNSCHWEIG,GERMANY

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 06期

关键词：

P – P bond formation; Tetramethyldiphosphine monosulfide; Tetraphenyldiphosphine monosulfide; Thiourea;

D O I：

10.1002/cber.19901230615

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A New Mode of Formation of a Phosphorus ‐ Phosphorus Bond. X‐ray Crystal Structure of Tetramethyldiphosphane Monosulfide Tetraphenyldiphosphane monosulfide (7) was formed during an attempt to synthesize the diphenylphosphino‐substituted thioureas 5 and 6 by the reaction of thiourea (1) or N,N′‐bis‐(trimethylsilyl)thiourea (2) with chlorodiphenylphosphane. The attempted distillation of the dimethylphosphino‐substituted N,N′‐dimethylthiourea 9 furnished tetramethyldiphos‐phane monosulfide (10). These reactions provide a new mode of formation of phosphorus – phosphorus bonds. – According to an X‐ray analysis, 10 crystallizes in the space group P21/n. The molecule adopts a trans configuration, with the S atom antiperiplanar to the lone pair. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1313 / 1317

页数：5

共 23 条

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