INTRAMOLECULAR AND INTERMOLECULAR FERROMAGNETIC INTERACTION OF TRANSITION-METAL COMPLEXES CONTAINING PYRIMIDINE OR PYRAZINE DERIVATIVES

被引：23

作者：

ISHIDA, T

MITSUBORI, S

NOGAMI, T

ISHIKAWA, Y

YASUI, M

IWASAKI, F

IWAMURA, H

TAKEDA, N

ISHIKAWA, M

机构：

[1] UNIV TOKYO, FAC SCI, DEPT CHEM, BUNKYO KU, TOKYO 113, JAPAN

[2] UNIV TOKYO, INST SOLID STATE PHYS, MINATO KU, TOKYO 106, JAPAN

来源：

SYNTHETIC METALS | 1995年 / 71卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)03052-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The 1/2 spins of oxovanadium(IV) ions were ferromagnetically coupled with J/k(B) = +1.1 similar to+2.7 K in the dinuclear complexes L[VO(hfac)(2)](2) (hfac = hexafluoroacetylacetonate, L = pyrimidine derivatives). Among them, a ferromagnetic transition was observed at about 0.14 K in PM[VO(hfac)(2)](2) (PM = pyrimidine). The polymeric complex QZ[Cu(hfac)(2)] (QZ = quinazoline) gave a positive Weiss constant (+0.39 K). The ferromagnetic transition was observed at about 0.12 K.

引用

页码：1791 / 1792

页数：2

共 7 条

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