ON MECHANISM OF ELECTROLYTIC REDUCTION OF CARBON-HALOGEN BOND .2. A RHOSIGMA STUDY

被引：102

作者：

SEASE, JW

BURTON, FG

NICKOL, SL

机构：

[1] Department of Chemistry, Wesleyan University, Middletown

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 10期

关键词：

D O I：

10.1021/ja01012a026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Plots of polarographic half-wave potentials in dimethylformamide and acetonitrile vs. σ for substituted chlorobenzenes, bromobenzenes, iodobenzenes, and benzyl bromides indicate a negatively charged potentialdetermining transition state. These and similar results by others rule out an SN1-type mechanism. © 1968, American Chemical Society. All rights reserved.

引用

页码：2595 / &

共 23 条

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