FLOW DYNAMICS OF SUPERSONIC MOLECULAR-BEAMS AND THE MEASUREMENT OF ROTATIONAL TRANSLATIONAL COUPLING PARAMETERS FOR N-2 AND H-2

被引:7
作者
CAMERON, BR
HARLAND, PW
机构
来源
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 08期
关键词
D O I
10.1039/ft9918701069
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Collision frequency, flow velocity, particle density, mean-free path, axial and radial temperatures in supersonic atomic and homonuclear diatomic beams have been calculated for various species within the framework of the thermal conduction model using realistic interaction potentials and collision cross-sections obtained from scattering theory. Comparison between numerical results and measured velocity distributions are made to estimate values of rotational-translational coupling parameters for N2 and H-2.
引用
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页码:1069 / 1073
页数:5
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