PROTONATION OF THE IRON-SULFUR CORE IN [FE(4)S(4)X(4)](2-) (X=CL OR BR) - CHEMICAL PRECEDENT FOR THE ELEMENTARY REACTION OF THE HYDROGENASES AND NITROGENASES

被引:26
作者
HENDERSON, RA
OGLIEVE, KE
机构
关键词
D O I
10.1039/c39940000377
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Kinetic studies on [Fe(4)S(4)X(4)](2-) (X = Cl Or Br) show that the substitution of the first halide for thiolate is catalysed by protonation of the Fe4S4 cubane core, this is the first demonstration that these cores will bind protons.
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页码:377 / 379
页数:3
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