PROTONATION OF THE IRON-SULFUR CORE IN [FE(4)S(4)X(4)](2-) (X=CL OR BR) - CHEMICAL PRECEDENT FOR THE ELEMENTARY REACTION OF THE HYDROGENASES AND NITROGENASES

被引：26

作者：

HENDERSON, RA

OGLIEVE, KE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 04期

关键词：

D O I：

10.1039/c39940000377

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic studies on [Fe(4)S(4)X(4)](2-) (X = Cl Or Br) show that the substitution of the first halide for thiolate is catalysed by protonation of the Fe4S4 cubane core, this is the first demonstration that these cores will bind protons.

引用

页码：377 / 379

页数：3

共 6 条

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[5] KINETIC-STUDIES ON [(MFE3S4(SR)3)2(MU-SR)3]3- (M = MO OR W, R = ET OR PH) - INFLUENCE OF MO OR W ON THE MECHANISM OF SUBSTITUTION AT THE IRON CENTERS WITHIN THE CLUSTER
HENDERSON, RA
OGLIEVE, KE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (10): : 1473 - 1476
[6] HENDERSON RA, 1993, J CHEM SOC DALTON, P1467

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