SYNTHESIS, CHARACTERIZATION AND METAL SORPTION STUDIES OF A CHELATING RESIN FUNCTIONALIZED WITH N-HYDROXYETHYLETHYLENEDIAMINE LIGANDS

被引：22

作者：

DEV, K ^{[1
]}

RAO, GN ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,NEW DELHI 110016,INDIA

来源：

ANALYST | 1995年 / 120卷 / 10期

关键词：

METAL SORPTION; CHELATING RESIN; N-HYDROXYETHYLENEDIAMINE LIGAND; ATOMIC ABSORPTION SPECTROMETRY;

D O I：

10.1039/an9952002509

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A poly[styrene-co-(divinyl benzene)] resin (XAD-4) functionalized with N-hydroxyethylethylenediamine ligands has been synthesized and its application for the concentration and separation of trace amounts of metal ions was studied, Metal sorption studies were carried out with Cu-II, Ni-II, Zn-II, Co-II, Fe-II, Cd-II, Pb-II, Mn-II and Cr-III as a function of pH. Trace amounts of these metal ions were quantitatively retained on the resin and recovered by eluting with 1 mol l(-1) hydrochloric acid, The resin was found to be selective for Pb-II and Cu-II, and their separation from other metal ions in the binary mixture was carried out effectively, Metal ion concentrations were determined using AAS.

引用

页码：2509 / 2512

页数：4

共 13 条

[1] ION-EXCHANGE SEPARATION AND DETERMINATION OF CALCIUM AND MAGNESIUM
ARGUELLO, MD
FRITZ, JS
[J]. ANALYTICAL CHEMISTRY, 1977, 49 (11) : 1595 - 1598
[2] CHEMISTRY OF METAL COMPLEXES WITH POLYDENTATE LIGANDS . COMPLEXES OF N-HYDROXYETHYLETHYLENEDIAMINE
DASSARMA, B
BAILAR, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (22) : 5958 - &
[3] CHARACTERIZATION OF CALCIUM FORM OF CHELEX-100 FOR TRACE-METAL STUDIES
FIGURA, P
MCDUFFIE, B
[J]. ANALYTICAL CHEMISTRY, 1977, 49 (13) : 1950 - 1953
[4] SOME CHELATING ION-EXCHANGE RESINS CONTAINING KETOIMINOCARBOXYLIC ACIDS AS FUNCTIONAL GROUPS
MARHOL, M
CHENG, KL
[J]. TALANTA, 1974, 21 (07) : 751 - 762
[5] PRECONCENTRATION AND SEPARATION OF METAL-IONS ON AN N-PHENYLHYDROXAMIC ACID RESIN
MENDEZ, R
PILLAI, VNS
[J]. ANALYST, 1990, 115 (02) : 213 - 216
[6] PREPARATION AND ANALYTICAL APPLICATIONS OF A PROPYLENEDIAMINETETRAACETIC ACID RESIN
MOYERS, EM
FRITZ, JS
[J]. ANALYTICAL CHEMISTRY, 1977, 49 (03) : 418 - 423
[7] SEPARATION OF METAL-IONS USING A HEXYLTHIOGLYCOLATE RESIN
MOYERS, EM
FRITZ, JS
[J]. ANALYTICAL CHEMISTRY, 1976, 48 (08) : 1117 - 1120
[8] SEPARATION OF MOLYBDENUM(VI) AND VANADIUM(V) BY USE OF POLYSTYRENE RESINS WITH A FUNCTIONAL-GROUP HAVING BIS(2-HYDROXYETHYL)AMINO AND BIS(PHOSPHONOMETHYL)AMINO MOIETY
NISHIZAWA, M
YOKOYAMA, T
KIMURA, T
SUZUKI, TM
[J]. CHEMISTRY LETTERS, 1983, (09) : 1413 - 1414
[9] PREPARATION AND CHROMATOGRAPHIC APPLICATIONS OF AN AMIDE RESIN
ORF, GM
FRITZ, JS
[J]. ANALYTICAL CHEMISTRY, 1978, 50 (09) : 1328 - 1330
[10] Silverstein R., 1991, SPECTROMETRIC IDENTI, P120

← 1 2 →