ALKALINE POLY(ETHYLENE OXIDE) SOLID POLYMER ELECTROLYTES - APPLICATION TO NICKEL SECONDARY BATTERIES

被引：108

作者：

FAUVARQUE, JF ^{[1
]}

GUINOT, S ^{[1
]}

BOUZIR, N ^{[1
]}

SALMON, E ^{[1
]}

PENNEAU, JF ^{[1
]}

机构：

[1] EDF,DEPT ETUD & RECH LES RENARDIERES,MORET SUR LOING,FRANCE

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 13-14期

关键词：

ALKALINE SOLID POLYMER ELECTROLYTE; POLY(ETHYLENE OXIDE); IONIC CONDUCTIVITY; NICKEL SECONDARY BATTERIES;

D O I：

10.1016/0013-4686(95)00212-W

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Water-containing and anhydrous alkaline PEG-based solid polymer electrolytes have been prepared, involving two different technologies. They exhibit a high ionic conductivity, and values up to 10(-3) S cm(-1) are obtained for some compositions at room temperature. Conductivity studies and thermal analysis are presented, and the conductivity vs. temperature behaviour of each type of solid polymer electrolyte studied is discussed. Preliminary results are reported concerning the cyclability of cells involving a nickel positive electrode, and a cadmium or a zinc negative electrode.

引用

页码：2449 / 2453

页数：5