COMPLEXES OF MANGANESE AND ZINC DI-TERT-BUTYLNAPHTHALENESULFONATE WITH CYCLOHEXANO-15-CROWN-5 ETHER TOLUENE SOLVATE

(1) Bis(3,7-di-tert-butylnaphthalenesulfonato)(2,5,8,11,14-pentaooxabicyclo[13.4.0]nona- decane)manganese monohydrate toluene (1/1), Mn-(C18H23O3S)2(C14H26O5).H2O.C7H8, M(r) = 1078.33, monoclinic, P2(1)/c, a = 12.737 (1), b = 39.460 (4), c = 12.765 (1) angstrom, beta = 116.40 (1)-degrees, V = 5747 (2) angstrom 3, Z = 4, D(m) = 1.24, D(x) = 1.25 g cm-3, lambda(Mo K-alpha) = 0.71069 angstrom, mu = 3.47 cm-1, F(000) = 2308, T = 297 K, R(F) = 0.069 for 3060 reflections [I > 2-sigma(I)]. (2) Bis(3,7-di-tert-butylnaphthalenesulfonato)-(2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadecane)zinc monohydrate toluene (1/1), Zn(C18H23O3S)2(C14H26O5).H2O.C7H8, M(r) = 1088.77, monoclinic, P2(1)/c, a = 12.766 (2), b = 39.083 (5), c = 12.771 (2) angstrom, beta = 116.44 (1)-degrees, V = 5705 (2) angstrom 3, Z = 4, D(m) = 1.28, D(x) = 1.27 g cm-3, lambda(Mo K-alpha) = 0.71069 angstrom, mu = 5.69 cm-1, F(000) = 2328, T = 297 K, R(F) = 0.067 for 2240 reflections [I > 2-sigma(I)]. Complexes are isostructural. The cation is inside the crown and bonded to its five O atoms and to one O atom of a sulfonate and to one water molecule, forming a pentagonal bipyramid coordination. The second sulfonate ion is hydrogen bonded to the water. There is disorder affecting a tert-butyl group and possibly the toluene solvate.