APPLICATION OF NMR-SPECTROSCOPY TO THE CHARACTERIZATION OF ELASTOMER FILLER INTERACTIONS

被引：36

作者：

LEGRAND, AP ^{[1
]}

LECOMTE, N ^{[1
]}

VIDAL, A ^{[1
]}

HAIDAR, B ^{[1
]}

PAPIRER, E ^{[1
]}

机构：

[1] CNRS,CTR RECH PHYSICOCHIM SURFACES SOLIDES,F-68200 MULHOUSE,FRANCE

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1992年 / 46卷 / 12期

关键词：

D O I：

10.1002/app.1992.070461220

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Proton spin-spin relaxation time measurements have been performed at 300 and 400 MHz on bound rubber-filler mixes resulting from the solvent extraction of silica-filled and silica-filled-modified polybutadiene, on the one hand, and of carbon black-filled and carbon black-filled-modified styrene butadiene rubber, on the other hand. Two relaxation times are observed for all samples. They are ascribed to the occurrence of tightly and loosely bound rubber components, respectively. The effect of the grafting modification of the fillers on the formation of bound rubber and its two components is discussed.

引用

页码：2223 / 2232

页数：10

共 16 条

[1] CHARACTERIZATION OF CHEMICALLY MODIFIED SILICA-GELS BY SI-29 AND C-13 CROSS-POLARIZATION AND MAGIC ANGLE SPINNING NUCLEAR MAGNETIC-RESONANCE [J].

BAYER, E ;

ALBERT, K ;

REINERS, J ;

NIEDER, M ;

MULLER, D .

JOURNAL OF CHROMATOGRAPHY, 1983, 264 (02) :197-213

[2] IDENTIFICATION OF RATES AND AMPLITUDES OF MACROMOLECULAR MOTIONS IN CIS-1,4-POLYBUTADIENE WITH COHERENT AVERAGING METHODS [J].

ENGLISH, AD ;

DYBOWSKI, CR .

MACROMOLECULES, 1984, 17 (03) :446-449

[3] PULSED NMR-STUDY ON THE SILICA-FILLED RUBBER SYSTEMS [J].

ITO, M ;

NAKAMURA, T ;

TANAKA, K .

JOURNAL OF APPLIED POLYMER SCIENCE, 1985, 30 (08) :3493-3504

[4] NUCLEAR MAGNETIC RESONANCE STUDY OF RUBBER-CARBON BLACK INTERACTIONS [J].

KAUFMAN, S ;

SLICHTER, WP ;

DAVIS, DD .

JOURNAL OF POLYMER SCIENCE PART A-2-POLYMER PHYSICS, 1971, 9 (05) :829-&

[5] MAGIC ANGLE SPINNING C-13 NMR-STUDIES OF FILLED VULCANIZATES [J].

KOMOROSKI, RA .

RUBBER CHEMISTRY AND TECHNOLOGY, 1983, 56 (05) :959-970

[6]

KRAUS G, 1978, RUBBER CHEM TECHNOL, V51, P297, DOI 10.5254/1.3545836

[7] THERMAL EXPANSION, FREE VOLUME, AND MOLECULAR MOBILITY IN A CARBON BLACK-FILLED ELASTOMER [J].

KRAUS, G ;

GRUVER, JT .

JOURNAL OF POLYMER SCIENCE PART A-2-POLYMER PHYSICS, 1970, 8 (04) :571-&

[8] HYDROXYLS OF SILICA POWDERS [J].

LEGRAND, AP ;

HOMMEL, H ;

TUEL, A ;

VIDAL, A ;

BALARD, H ;

PAPIRER, E ;

LEVITZ, P ;

CZERNICHOWSKI, M ;

ERRE, R ;

VANDAMME, H ;

GALLAS, JP ;

HEMIDY, JF ;

LAVALLEY, JC ;

BARRES, O ;

BURNEAU, A ;

GRILLET, Y .

ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1990, 33 (2-4) :91-330

[9] CONTRIBUTION OF SOLID-STATE NMR-SPECTROSCOPY TO THE CHARACTERIZATION OF MATERIALS [J].

LEGRAND, AP ;

HOMMEL, H ;

TAIBI, H ;

MIQUEL, JL ;

TOUGNE, P .

COLLOIDS AND SURFACES, 1990, 45 :391-411

[10] INVERSE GAS-CHROMATOGRAPHY - A VALUABLE METHOD FOR THE SURFACE CHARACTERIZATION OF FILLERS FOR POLYMERS (GLASS-FIBERS AND SILICAS) [J].

PAPIRER, E ;

BALARD, H ;

VIDAL, A .

EUROPEAN POLYMER JOURNAL, 1988, 24 (08) :783-790

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