HIGHLY DISPERSED METAL-CLUSTERS AND COLLOIDS FOR THE PREPARATION OF ACTIVE LIQUID-PHASE HYDROGENATION CATALYSTS

被引：61

作者：

BONNEMANN, H

BRIJOUX, W

BRINKMANN, R

DINJUS, E

FRETZEN, R

JOUSSEN, T

KORALL, B

机构：

[1] Max-Planck-Institut für Kohlenforschung, W-4330 Mülheim an der Ruhr

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 74卷 / 1-3期

关键词：

D O I：

10.1016/0304-5102(92)80250-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A comparison of the activities of conventionally precipitated metals on charcoal, deposited organometallic clusters and metal colloids for liquid-phase hydrogenation has been made under standard conditions in order to assess the effect of particle size. The strong SMSI effect known for TiO2 SUPports was simulated on charcoal by doping the surface with small amounts of Ti(0) and subsequent oxygenation.

引用

页码：323 / 333

页数：11

共 38 条

[1] EFFECTS OF THE INTERACTION OF DISPERSED METAL PARTICLES WITH THE SUPPORT IN CATALYSTS PREPARED USING ORGANOMETALLIC COMPOUNDS
ALEKSEEV, OS
ZAIKOVSKII, VI
RYNDIN, YI
[J]. APPLIED CATALYSIS, 1990, 63 (01): : 37 - 50
[2] ANTONY MT, 1975, J CHEM SOC DA, P1419
[3] FORMATION OF COLLOIDAL TRANSITION-METALS IN ORGANIC PHASES AND THEIR APPLICATION IN CATALYSIS
BONNEMANN, H
BRIJOUX, W
BRINKMANN, R
DINJUS, E
JOUSSEN, T
KORALL, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (10): : 1312 - 1314
[4] Bonnemann H., 1991, ANGEW CHEM, V103, P1344
[5] BRADLEY JS, 1983, ADV ORGANOMET CHEM, V22, P1
[6] CLUSTERS, COLLOIDS AND CATALYSIS
BRADLEY, JS
HILL, E
LEONOWICZ, ME
WITZKE, H
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (1-2): : 59 - 74
[7] DEJONGH LJ, 1989, Z PHYS D ATOM MOL CL, V12, P445, DOI 10.1007/BF01426993
[8] DEJONGH LJ, 1987, NATO ASI SER B, V158, P807
[9] PREPARATION OF BIMETALLIC PD-PT COLLOIDS IN ORGANIC-SOLVENT BY SOLVENT-EXTRACTION REDUCTION
ESUMI, K
SHIRATORI, M
ISHIZUKA, H
TANO, T
TORIGOE, K
MEGURO, K
[J]. LANGMUIR, 1991, 7 (03) : 457 - 459
[10] Hegedus L. L., 1987, CATALYST DESIGN

← 1 2 3 4 →