A GENERAL SURVEY ON THE ANODIC BEHAVIOR OF AROMATIC THIOETHERS IN ORGANIC-SOLVENTS OF LOW NUCLEOPHILICITY

被引:14
作者
ELINSON, MN
SIMONET, J
TOUPET, L
机构
[1] UNIV RENNES 1,CNRS,ELECTROCHIM ORGAN LAB 439,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE
[2] UNIV RENNES 1,CNRS,URA 804,MAT CONDENSEE & MAT GRP,F-35042 RENNES,FRANCE
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 350卷 / 1-2期
关键词
D O I
10.1016/0022-0728(93)80200-2
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Aromatic sulfides were oxidized electrochemically in super-dry conditions. Whatever the nature of aryl groups, the formation of sulfonium salts was observed. Dimeric dications as transients were also detected. Mechanisms are discussed as a function of the nature and location of substituents.
引用
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页码:117 / 132
页数:16
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