MONO-ETA-CYCLOPENTADIENYL-BENZAMIDINATO COMPOUNDS OF TITANIUM, ZIRCONIUM AND HAFNIUM

被引：49

作者：

CHERNEGA, AN

GOMEZ, R

GREEN, MLH

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期

关键词：

D O I：

10.1039/c39930001415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new compounds [M(eta-C5R5){eta-R'NC(Ph)NR'}Cl2] [where R'= Me3Si (TMS), and R = H, M = Ti, Zr, H for R = Me,M = Ti or Zr], [Zr(eta-C5R5){(eta-R'NC(Ph)NR'}(CH2Ph)Cl] (R = H, Me), and [Zr(eta-C5R5){eta-R'NC(Ph)NR)(CH2Ph)2] (R = H, Me) are described; the compound [Zr(eta-C5H5){eta-R'C(Ph)R'}Cl2] acts as a cocatalyst for the polymerisation of ethylene and propene.

引用

页码：1415 / 1417

页数：3

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