STRONTIUM DICOBALT ORTHOPHOSPHATE

被引：29

作者：

ELBALI, B

BOUKHARI, A

HOLT, EM

ARIDE, J

机构：

[1] OKLAHOMA STATE UNIV,DEPT CHEM,STILLWATER,OK 74078

[2] ENS TAKADDOUM,PHYSICOCHIM MAT LAB,RABAT,MOROCCO

来源：

JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH | 1993年 / 23卷 / 12期

关键词：

D O I：

10.1007/BF01185551

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In crystalline SrCo2(PO4)(2); triclinic P ($) over bar 1, M(r)=395.4, a=5.014(2), b=8.639(4), c=9.691(1)Angstrom, alpha=118.04(3), beta=75.09(4), gamma=86.90(4)degrees, V=350.4(3)Angstrom(3), Z=2, D-calc=3.747 g cm(-3), lambda Mo K alpha=0.71069 Angstrom, mu=12.49 mm(-1), F(000)=372, T=298 K, R=4.1% for 1190 obs. reflections; Co2+ and PO43- ions are found on planes parallel to (001). Co2+ occupies sites of four- and five-(trigonal bipyramidal) coordination with average Co-O distances, 1.948(8) and 2.087(8)Angstrom, respectively. The blue color of solid is due to the tetrahedral coordination geometry of the four-coordinate copper atoms.

引用

页码：1001 / 1004

页数：4

共 28 条

[1] THE CRYSTAL-STRUCTURE OF CA3CU3(PO4)4
ANDERSON, JB
KOSTINER, E
RUSZALA, FA
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1981, 39 (01) : 29 - 34
[2] CRYSTAL-STRUCTURE OF COBALT ORTHOPHOSPHATE CO3(PO4)2
ANDERSON, JB
KOSTINER, E
MILLER, MC
REA, JR
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1975, 14 (04) : 372 - 377
[3] A HIGH-PRESSURE PHASE OF MAGNESIUM ORTHO-PHOSPHATE
ANNERSTEN, H
NORD, AG
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1980, 34 (05): : 389 - 390
[4] Blessing R. H., 1986, CRYSTALLOGR REV, V1, P3
[5] A NEW LINEAR TRIMERIC MAGNETIC ION IN (CA,SR)3CU3(PO4)4 PHOSPHATES
BOUKHARI, A
MOQINE, A
FLANDROIS, S
[J]. MATERIALS RESEARCH BULLETIN, 1986, 21 (04) : 395 - 400
[6] SYNTHESIS AND CRYSTALLIZATION OF BANI2(PO4)2
CABRIC, B
ZIZIC, B
NAPIJALO, ML
[J]. JOURNAL OF CRYSTAL GROWTH, 1982, 60 (01) : 169 - 171
[7] CRYSTAL STRUCTURE OF ALPHA-ZN3(PO4)2
CALVO, C
[J]. CANADIAN JOURNAL OF CHEMISTRY, 1965, 43 (02): : 436 - &
[8] STRUCTURE OF NICKEL ORTHOPHOSPHATE
CALVO, C
FAGGIANI, R
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (10): : 1516 - 1520
[9] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS
CROMER, DT
MANN, JB
[J]. ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 : 321 - &
[10] CRYSTALLOGRAPHIC STUDIES OF ROLE OF MG AS A STABILIZING IMPURITY IN BETA-CA3(PO4)2 .1. CRYSTAL-STRUCTURE OF PURE BETA-CA3(PO4)2
DICKENS, B
SCHROEDER, LW
BROWN, WE
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1974, 10 (03) : 232 - 248

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