REVERSAL OF THE ORTHO-PARA-ISOMER RATIOS BY ALTERING THE INITIAL CONCENTRATION OF SUBSTRATE IN THE OZONE-MEDIATED NITRATION OF CHLORO-BENZENE AND BROMO-BENZENE

被引：8

作者：

SUZUKI, H ^{[1
]}

MORI, T ^{[1
]}

MAEDA, K ^{[1
]}

机构：

[1] NISSAN CHEM IND CO LTD,CENT RES INST,FUNABASHI,CHIBA 274,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 17期

关键词：

D O I：

10.1039/c39930001335

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ortho-para-isomer ratios of the nitration products can be reversed from ortho-rich (o/p = 1.10 and 1.09) to para-predominant (o/p = 0.45 and 0.68) simply by altering the initial concentration of the substrate in the ozone-mediated reaction of chloro- and bromo-benzenes with nitrogen dioxide.

引用

页码：1335 / 1337

页数：3

共 12 条

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